P. Puomi et al., Effect of skin pass rolling on the primer adhesion and corrosion resistance of hot-dip galvanized (HDG) steel, J ADHES SCI, 14(4), 2000, pp. 583-600
By using three different skin pass reductions, 0%, 0.75%, and 1.5%, the inf
luence of skin pass rolling on the primer adhesion and corrosion resistance
of primed hot-dip galvanized (HDG) steel has been studied. The corrosion r
esistance of primed panels was determined by a cyclic prohesion test, and t
he primer adhesion was examined with a combined cross-cut and impact test.
Surface roughness was determined for untreated and pretreated skin passed p
anels and the samples were also studied using an optical microscope and a s
canning electron microscope. Electron spectroscopy for chemical analysis (E
SCA) and glow discharge optical emission spectroscopy (GD-OES) were used to
characterize the chemical surface composition of the panels. According to
the prohesion test results, the roughest samples showed the best corrosion
resistance and also slightly improved adhesion test results. The ESCA and G
D-OES results showed that the outermost surface was enriched by aluminium i
n the zinc coating. During skin pass rolling, the aluminium oxide-rich surf
ace is broken and zinc is revealed to the surface. An increase in the skin
pass reduction resulted in an almost linear increase in the surface roughne
ss. Mechanical removal of the surface aluminium also affected the amount of
aluminium dissolved during the chemical pretreatment. The best results obt
ained for the roughest samples are mainly due to the most homogeneous skin
pass pattern obtained with the highest skin pass reduction.