Effect of skin pass rolling on the primer adhesion and corrosion resistance of hot-dip galvanized (HDG) steel

Citation
P. Puomi et al., Effect of skin pass rolling on the primer adhesion and corrosion resistance of hot-dip galvanized (HDG) steel, J ADHES SCI, 14(4), 2000, pp. 583-600
Citations number
17
Categorie Soggetti
Material Science & Engineering
Journal title
JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY
ISSN journal
01694243 → ACNP
Volume
14
Issue
4
Year of publication
2000
Pages
583 - 600
Database
ISI
SICI code
0169-4243(2000)14:4<583:EOSPRO>2.0.ZU;2-0
Abstract
By using three different skin pass reductions, 0%, 0.75%, and 1.5%, the inf luence of skin pass rolling on the primer adhesion and corrosion resistance of primed hot-dip galvanized (HDG) steel has been studied. The corrosion r esistance of primed panels was determined by a cyclic prohesion test, and t he primer adhesion was examined with a combined cross-cut and impact test. Surface roughness was determined for untreated and pretreated skin passed p anels and the samples were also studied using an optical microscope and a s canning electron microscope. Electron spectroscopy for chemical analysis (E SCA) and glow discharge optical emission spectroscopy (GD-OES) were used to characterize the chemical surface composition of the panels. According to the prohesion test results, the roughest samples showed the best corrosion resistance and also slightly improved adhesion test results. The ESCA and G D-OES results showed that the outermost surface was enriched by aluminium i n the zinc coating. During skin pass rolling, the aluminium oxide-rich surf ace is broken and zinc is revealed to the surface. An increase in the skin pass reduction resulted in an almost linear increase in the surface roughne ss. Mechanical removal of the surface aluminium also affected the amount of aluminium dissolved during the chemical pretreatment. The best results obt ained for the roughest samples are mainly due to the most homogeneous skin pass pattern obtained with the highest skin pass reduction.