Preconcentration of noble metals on a polymer support as complexes of organic reagents and their subsequent determination in the solid phase

Conditions of the sorption preconcentration of Pt, Pd, Au, Ag, and Bg as co lored complexes of azorhodanines, tyrodine, and sulfonitrophenol M from aci dic solutions (pH 0-2) on a polyamide membrane in the flow mode are determi ned. At a flow rate of 10-20 mL/min, concentrations of determined elements of 10(-9)-10(-7) M, and pressure of 10-20 mm Hg, the complexes are nearly q uantitatively sorbed on a polyamide membrane disk (d = I cm, m = 2.7 mg, an d I = 0.1 mm). The influence of the composition of the test solutions on th e formation of the analytical signal in the solid phase is studied. Rapid s orption-spectrometric procedures are developed for the determination of Pt, Pd, Au, Ag, and Ag with the detection limit 5-30 ng of the element in the sorbent zone.