GOLD(I) COMPLEXES WITH BIOLOGICALLY-ACTIVE THIOLATE LIGANDS

Authors
GIMENO MC JAMBRINA E FERNANDEZ EJ LAGUNA A LAGUNA M JONES PG MERCHAN FL TERROBA R
Citation
Mc. Gimeno et al., GOLD(I) COMPLEXES WITH BIOLOGICALLY-ACTIVE THIOLATE LIGANDS, Inorganica Chimica Acta, 258(1), 1997, pp. 71-75
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
258
Issue
1
Year of publication
1997
Pages
71 - 75
Database
ISI
SICI code
0020-1693(1997)258:1<71:GCWBTL>2.0.ZU;2-Q
Abstract
The reaction of ethanolic solutions of Na(SR) (SR=4-oxo-2-thioxopyrimi dines) with [AuCIL] (L=PPh3, PPh2Me and AsPh3) gives [Au(SR)L]; when P PN[AuCl2] or NBu4[AuBr(C6F5)] are used instead, PPN[Au(SR)(2)] and NBu 4[Au(C6F5)(SR)] are obtained. The structure of [Au(SR1)(PPh3)] has bee n established by X-ray diffraction, and shows a linear coordination at gold involving the phosphine phosphorus and the exocyclic sulfur atom of the organic ligand.