THE CRYSTAL-STRUCTURE OF 3-BUTENYLTRIPHENYLSTANNANE - CRYSTAL DISORDER AND THERMODYNAMIC PROPERTIES

Authors
GANIS P VALLE G MARTON D TAGLIAVINI G
Citation
P. Ganis et al., THE CRYSTAL-STRUCTURE OF 3-BUTENYLTRIPHENYLSTANNANE - CRYSTAL DISORDER AND THERMODYNAMIC PROPERTIES, Inorganica Chimica Acta, 258(1), 1997, pp. 119-121
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
258
Issue
1
Year of publication
1997
Pages
119 - 121
Database
ISI
SICI code
0020-1693(1997)258:1<119:TCO3-C>2.0.ZU;2-S
Abstract
The tin derivative 3-butenyltriphenylstannane [Ph3Sn-CH2-CH2-CH=CH2] ( A) has been prepared; the crystal and molecular structure has been det ermined by X-ray analysis. The compound crystallizes in the tetragonal space group P (4) over bar 2(1)c with a=b=11.860(3), c=6.839(2) Angst rom, Z=2. Refinement converged to the final R index 0.044. The crystal and physical data are compared with those of tetraphenyltin (B); the relevant differences are explained in terms of structural disorder.