Electroosmotic phenomena in fractures have been investigated in the linear
limit for various double-layer thicknesses. The effects of the geometrical
parameters were systematically studied for deterministic sinusoidal and ran
dom self-affine fractures. The numerical results show a definite influence
of the surface amplitude on electroosmotic processes. For self-affine fract
ures, the roughness or Hurst exponent has a much larger incidence than the
correlation parameter between the two surfaces. All the electroosmotic coup
ling coefficients can be gathered in a single relationship which depends on
a characteristic length scale Lambda, applicable to every configuration. S
uch a length was already found useful for porous media, but the relationshi
p is different. (C) 2000 Academic Press.