The synthesis, mesomorphism and mesophase structure of anisotropic imines and their complexes with rhenium(I)

Citation
Xh. Liu et al., The synthesis, mesomorphism and mesophase structure of anisotropic imines and their complexes with rhenium(I), J MAT CHEM, 10(3), 2000, pp. 637-644
Citations number
21
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
JOURNAL OF MATERIALS CHEMISTRY
ISSN journal
09599428 → ACNP
Volume
10
Issue
3
Year of publication
2000
Pages
637 - 644
Database
ISI
SICI code
0959-9428(2000)10:3<637:TSMAMS>2.0.ZU;2-U
Abstract
Highly anisotropic imine ligands have been synthesised and complexed to Re( I). Two series of ligands and complexes were obtained with various chain le ngths, showing smectic and nematic phases for the ligands and only a nemati c phase for the complexes. The identity of the crystal smectic phase in the ligands was studied by X-ray diffraction and identified as a crystal J pha se.