Step-wise adsorption of polyelectrolytes is used for the fabrication of mic
ro- and nanocapsules with determined size, capsule wall composition and thi
ckness. The capsule walls made of polyelectrolyte multilayers exclude high
molecular weight compounds. Assembling of lipid layers onto these polyelect
rolyte capsules prevents the permeation of small dyes. Encapsulation of mag
netite nanoparticles is demonstrated and the features of these novel capsul
es are discussed.