The optical band gap and optical constants have been studied as a function
of photon energy for a-GaxSe100-x thin films (where x = 0. 2.5, 5.0, 7.5 an
d 10.0) in the wavelength region 450-1000nm. The optical band gap decreases
with the increase of Ga concentration in the a-GaxSe100-x system. The refr
active index (n) decreases while the extinction coefficient (k) increases w
ith increasing photon energy. The results are interpreted in terms of conce
ntration of localized states.