Intramolecular hydrogen bonds in 3-diethylaminomethyl-5-R-salicylic aldehydes

Authors
Szady-Chelmieniecka, A Rozwadowski, Z Dziembowska, T Grech, E Wojciechowski, G Brzezinski, B
Citation
A. Szady-chelmieniecka et al., Intramolecular hydrogen bonds in 3-diethylaminomethyl-5-R-salicylic aldehydes, J MOL STRUC, 520, 2000, pp. 39-43
Citations number
15
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
520
Year of publication
2000
Pages
39 - 43
Database
ISI
SICI code
0022-2860(20000314)520:<39:IHBI3A>2.0.ZU;2-Z
Abstract
Two 3-diethylaminomethyl-5-R-salicylic aldehydes were obtained and studied in chloroform solutions by FTIR and NMR spectroscopy. The existence of an e quilibrium between the structures with OH ...=O=C and N ... HO intramolecul ar hydrogen bonds was suggested. In the ease of compound 1 (R = OCH3) the O H ... O=C intramolecular hydrogen bond was more favorable whereas in the ca se of compound 2 (R = Br) the structure with the OH ... N intramolecular hy drogen bond was predominant. (C) 2000 Elsevier Science B.V. All rights rese rved.