Photoluminescent macrocyclic Pd(II) and Pt(II) dimeric complexes with Ph2P-C C-PPh2 spacer

Authors
Xu, DF Murfee, HJ van der Veer, WE Hong, B
Citation
Df. Xu et al., Photoluminescent macrocyclic Pd(II) and Pt(II) dimeric complexes with Ph2P-C C-PPh2 spacer, J ORGMET CH, 596(1-2), 2000, pp. 53-63
Citations number
51
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
596
Issue
1-2
Year of publication
2000
Pages
53 - 63
Database
ISI
SICI code
0022-328X(20000229)596:1-2<53:PMPAPD>2.0.ZU;2-3
Abstract
The synthesis and characterization of macrocyclic Pd(II)/Pt(II) dimers and their monomeric precursors with diphosphine spacer Ph2P-C=C-PPh2 (C2P2) are reported. Their excited-state properties, including solvent-dependent abso rption, emission and quantum yield, are studied. When the solvent polarity increases, solvatochromic absorption band shifts to higher energy, emission maximum shifts to lower energy, and quantum yield decreases. In addition, the host-guest behavior of these new inorganic macrocycles is also reported here. (C) 2000 Elsevier Science S.A. All rights reserved.