Molecular modeling of dimetal systems - Part 4. Dirhenium bonds

Authors
Bacsa, J Boeyens, JCA
Citation
J. Bacsa et Jca. Boeyens, Molecular modeling of dimetal systems - Part 4. Dirhenium bonds, J ORGMET CH, 596(1-2), 2000, pp. 159-164
Citations number
12
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
596
Issue
1-2
Year of publication
2000
Pages
159 - 164
Database
ISI
SICI code
0022-328X(20000229)596:1-2<159:MMODS->2.0.ZU;2-E
Abstract
The relationship between bond order (N), harmonic force constant (k(r)) and characteristic bond length free of strain (r(0)) for dirhenium bonds has b een studied by molecular-mechanics simulation of suitable structures well c haracterized by X-ray diffraction. It follows the same trend, N = ak(r) = a br(0)(-5), found before for dimolybdenum and dichromium bonds. (C) 2000 Els evier Science S.A. All rights reserved.