S. Ganapathy et al., Two-dimensional solid state NMR and separation of Li-7 quadrupolar interactions in paramagnetic compounds, J PHYS CH A, 104(10), 2000, pp. 2007-2012
Ln layered paramagnetic compounds, such as La2Li0.5Ni0.5O4 with a perovskit
e structure, the Li-7 NMR spectrum is broadened by anisotropic quadrupolar
as well as paramagnetic dipolar interactions. We have used a two-dimensiona
l spin echo (SE) experiment to separate the quadrupolar interaction and obt
ain a clean quadrupolar spectrum along the wi dimension. This is demonstrat
ed in La2Li0.5B0.5O4 (B = Cu, Ni), through 2D SE experiments conducted in s
tatic samples as well as those in spinning at the magic angle. A quadrupole
coupling constant of 92 kHz is estimated from the Wi spectrum for paramagn
etic La2Li0.5Ni0.5O4.