Biodegradation of a sugar branched polymer consisting of sugar, fatty acid, and poly(vinyl alcohol)

Citation
Y. Tokiwa et al., Biodegradation of a sugar branched polymer consisting of sugar, fatty acid, and poly(vinyl alcohol), MACROMOLEC, 33(5), 2000, pp. 1636-1639
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULES
ISSN journal
00249297 → ACNP
Volume
33
Issue
5
Year of publication
2000
Pages
1636 - 1639
Database
ISI
SICI code
0024-9297(20000307)33:5<1636:BOASBP>2.0.ZU;2-B
Abstract
We have examined synthesis of sugar branched polymer as a biodegradable mat erial by utilizing natural substances. Biodegradation of a poly(vinyl alcoh ol) (PV-OH) having sugars and fatty acids was observed by a biochemical oxy gen demand (BOD) tester using the oxygen consumption method. PV-OH is known as a biodegradable polymer by PV-OH assimilating microbes that are not dis tributed widely. In this paper, the sugar branched polymers were degraded d epending upon the molecular weights, and the polymer having a molecular wei ght (M-n) of 3600 was degraded at 70-80% within 28 days by a soil or an act ivated sludge without addition of PV-OH assimilating microbes. This is beca use the proportion of PV-OH main chain in the molecular weight of the polym er is low. PV-OH with low molecular weight can be degraded without PV-OH as similating microbes. These results indicate that the polymer is completely biodegradable and may have application as a new type of water-soluble mater ial.