An. Streletskii et Th. Courtney, Kinetic, chemical and mechanical factors affecting mechanical alloying of Ni-bcc transition metal mixtures, MAT SCI E A, 282(1-2), 2000, pp. 213-222
The influence of enthalpy of mixing and elemental mechanical characteristic
s on the kinetics of mechanical alloying (MA) of 80 at.% Ni-20 at.% bcc tra
nsition metals (Fe, Cr, W, Nb, and Ta) has been studied. The features and s
tructures of milled powders were characterized by X-ray diffraction, optica
l microscopy, and particle size analysis. Powder caking of the grinding med
ia in varying amounts depending On the materials alloyed and the alloying t
ime - occurs when these elemental combinations are mechanically alloyed. Di
fferences, if any, between the structures of 'free' and 'caked' powders wer
e also determined. As expected, for systems with low enthalpies of mixing (
Ni/Fe, Ni/Cr, Ni/W) crystalline solid solutions form during MA. Moreover, t
he compositions of these solid solutions are the same in both free and cake
d powders. Also as anticipated, for systems with high enthalpies of mixing
(Ni/Nb, Ni/Ta), extended MA produces amorphous phases that form from precur
sor solid solutions. In distinction to systems with low enthalpies of mixin
g, the structures of the free and caked powders differ for systems with hig
h mixing enthalpies. Caked powders were inhomogeneous, consisting of powder
in varying degrees of solid solution and, if the milling time was sufficie
ntly long, also some amorphous powder. However, the free powder was almost
entirely noncrystalline With extended milling, the fraction of free powder
increases suggesting that the formation of the amorphous phase takes place
on the surface layer of the coated grinding media. Subsequent to its format
ion, the amorphous phase is abraded from the coated surfaces. The kinetics
of solid solution and/or amorphous phase formation is discussed in terms of
the differing mechanical characteristics of the bcc transition elements, a
s well as the system thermodynamics. (C) 2000 Elsevier Science S.A. All rig
hts reserved.