We review a polymeric waveguide technology developed to produce affordable
high-performance optical components that address the needs of both the tele
com and the datacom industries. We engineer advanced organic polymers that
can be readily made into planar single-mode, multimode, and micro-optical w
aveguide structures of controlled numerical apertures and geometries. These
materials are formed from highly crosslinked acrylate monomers with specif
ic linkages that determine properties such as flexibility, toughness, optic
al loss, and environmental stability, These monomers are intermiscible, pro
viding for precise continuous adjustment of the refractive index over a wid
e range. in polymer form, they exhibit state-of-the-art loss values. suppre
ssed polarization effects, and exceptional stability. enabling their use in
a variety of demanding applications. Waveguides are formed photolithograph
ically, with the liquid monomer mixture polymerizing upon illumination in t
he UV via either mask exposure or laser direct writing. A wide range of rig
id and flexible substrates can be used. The devices we describe include a v
ariety of passive and thermo-optically active elements that achieve a varie
ty of coupling, routing, and filtering functionalities. These devices can b
e either individually pigtailed and packaged components or they can be part
of a massively parallel photonic integrated circuit on the multichip modul
e (MCM), board, or backplane level. (C) 2000 Society of Photo-Optical Instr
umentation Engineers. [S0091-3286(00)01003-5].