Optical second-harmonic generation (SHG) is used as a noninvasive probe of
two-dimensional (2D) ferroelectricity in Langmuir-Blodgett (LB) films of th
e copolymer vinylidene fluoride with trifluoroethylene. The surface 2D ferr
oelectric - paraelectric phase transition in the topmost layer of the LB fi
lms and a thickness-independent (almost 2D) transition in the bulk of these
films are observed in temperature studies of SHG. (C) 2000 Optical Society
of America OCIS codes: 190.4350, 190.4710, 190.2620, 240.0310, 310.3840.