Charge transfer reactions involving highly charged ions up to U91+ are bein
g studied using x-ray spectroscopic techniques. The measurements are perfor
med using ions produced in situ in a cylindrical trap with very low kinetic
energy (less than or equal to 3 eV/amu). The observed K-shell and L-shell
x-ray emission show prominent features from high-n levels decaying to the g
round level. Such emission can serve as a diagnostic marker for charge tran
sfer processes in plasmas, for example in cometary comae or in ion traps. T
he emission is enabled by electron capture into states with low orbital ang
ular momentum, mainly l = 1. The observed spectra, thus, provide a handle o
n determining the fraction of electron capture into low-l states that can b
e used for testing theoretical model in the limit of low collision energy.
The present paper summarizes the progress made to date.