Synthesis of mono-, di-, and tri-phenyl arenes by sequential photostimulated S(RN)1 and Pd(0)-catalyzed cross coupling reactions on aryl halides

Authors
Corsico, EF Rossi, RA
Citation
Ef. Corsico et Ra. Rossi, Synthesis of mono-, di-, and tri-phenyl arenes by sequential photostimulated S(RN)1 and Pd(0)-catalyzed cross coupling reactions on aryl halides, SYNLETT, (2), 2000, pp. 230-232
Citations number
18
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
2
Year of publication
2000
Pages
230 - 232
Database
ISI
SICI code
0936-5214(200002):2<230:SOMDAT>2.0.ZU;2-A
Abstract
The photostimulated reaction of Me3Sn- ion with mono-, di-, and trichloro- arenes in liquid ammonia gave very good yields of stannanes by the S(RN)1 m echanism. These products reacted by a palladium-catalyzed cross coupling re action with halobenzenes to give phenylated products also in very good yiel ds. Similar yields can be obtained in one-pot reactions.