New parts for a construction set of bifunctional oligo(het)arylene building blocks for modular chemistry

Authors
Manickam, G Schluter, AD
Citation
G. Manickam et Ad. Schluter, New parts for a construction set of bifunctional oligo(het)arylene building blocks for modular chemistry, SYNTHESIS-S, (3), 2000, pp. 442-446
Citations number
20
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
SYNTHESIS-STUTTGART
ISSN journal
00397881 → ACNP
Issue
3
Year of publication
2000
Pages
442 - 446
Database
ISI
SICI code
0039-7881(200003):3<442:NPFACS>2.0.ZU;2-6
Abstract
The 100 mg to 5 g scale synthesis of a variety of arylene (6, 11, 13) and h etarylene building blocks (15, 17, 18) by and for Suzuki/Stille type cross- coupling reactions is reported. These building blocks carry solubilizing he xyloxymethyl substituents as well as boronic acid ester and Br/I functional ities. This considerably widens the already existing construction set for t he modular chemistry approach to shape persistent and functional compounds on the nanometer scale.