Optical properties of a new organic metal (BEDO-TTF)(5)[CsHg(SCN)(4)](2)

Citation
N. Drichko et al., Optical properties of a new organic metal (BEDO-TTF)(5)[CsHg(SCN)(4)](2), SYNTH METAL, 109(1-3), 2000, pp. 123-127
Citations number
13
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
03796779 → ACNP
Volume
109
Issue
1-3
Year of publication
2000
Pages
123 - 127
Database
ISI
SICI code
0379-6779(20000301)109:1-3<123:OPOANO>2.0.ZU;2-R
Abstract
Polarized reflectance and optical conductivity spectra of single crystals o f a new organic conductor based on the BEDO molecule, BEDO5[CsHg(SCN)(4)](2 ), were investigated in the 600-6500 cm(-1) and 9000-40000 cm(-1) range for the three principal axis at 300 K. Quasi-two-dimensional character of the conducting electronic system was established. The parameters of electronic system were obtained using the Drude model. The conducting bands of the inv estigated conductor appeared to be narrower than those of the recently inve stigated superconductor with the analogous structure, (BEDO-TTF)(2)ReO4(H2O ). An assignment of the vibrational features for all the investigated polar izations was proposed. (C) 2000 Elsevier Science S.A. All rights reserved.