Donor slab robustness and band filling variations in BDT-TTP-based molecular conductors: beta-(BDT-TTP)(6)[Re6S6Cl8]center dot(CH2Cl-CHCl2)(2) and beta-(BDT-TTP)(6)[Mo6Cl14]center dot(CH2Cl-CHCl2)(2)

Authors
Deluzet, A Batail, P Misaki, Y Auban-Senzier, P Canadell, E
Citation
A. Deluzet et al., Donor slab robustness and band filling variations in BDT-TTP-based molecular conductors: beta-(BDT-TTP)(6)[Re6S6Cl8]center dot(CH2Cl-CHCl2)(2) and beta-(BDT-TTP)(6)[Mo6Cl14]center dot(CH2Cl-CHCl2)(2), ADVAN MATER, 12(6), 2000, pp. 436
Citations number
26
Categorie Soggetti
Multidisciplinary,"Material Science & Engineering
Journal title
ADVANCED MATERIALS
ISSN journal
09359648 → ACNP
Volume
12
Issue
6
Year of publication
2000
Database
ISI
SICI code
0935-9648(20000316)12:6<436:DSRABF>2.0.ZU;2-U
Abstract
Communication: Two new phases for the metallic salts based on 2,5-bis(1,3-d ithiol-2-ylidene)-1,3,4,6-tetrathiapentalene have been prepared and shown t o exhibit metallic conductivity down to low temperature. The organic slab t opology and band structure are identical to previously determined 2:1 salts of the same donor with smaller monoanions-only the Fermi surface (see Figu re) is modified by changing the anion volume and charge.