L. Friedel et S. Korfmann, Predictive accuracy of design methods for the relief cross-sections for runaway reactions, CHEM-ING-T, 71(12), 1999, pp. 1370-1380
On the basis of calculations performed on the results of experiments conduc
ted in reactors with volumes up to 10 m(3) for so-called vapour-pressure pr
oducing (runaway) reaction systems, it is found that ail simplified or stea
dy-state methods regularly afford overdimensioned relief cross-sections. As
a consequence, unnecessarily large mass flows leave the reactor to enter t
he containment system. A balanced design of both plants components is possi
ble only with the aid of transient methods. In the case of gas generating r
eactions simplified methods also lead to excessively large pressure relief
cross-sections. Design with the aid of a transient method for such a reacti
on system is rendered difficult by the fact that a conservative submodel ca
nnot be used a priori for description of the expansion behaviour. A paramet
ric study is then required.