Predictive accuracy of design methods for the relief cross-sections for runaway reactions

Citation
L. Friedel et S. Korfmann, Predictive accuracy of design methods for the relief cross-sections for runaway reactions, CHEM-ING-T, 71(12), 1999, pp. 1370-1380
Citations number
32
Categorie Soggetti
Chemical Engineering
Journal title
CHEMIE INGENIEUR TECHNIK
ISSN journal
0009286X → ACNP
Volume
71
Issue
12
Year of publication
1999
Pages
1370 - 1380
Database
ISI
SICI code
0009-286X(199912)71:12<1370:PAODMF>2.0.ZU;2-T
Abstract
On the basis of calculations performed on the results of experiments conduc ted in reactors with volumes up to 10 m(3) for so-called vapour-pressure pr oducing (runaway) reaction systems, it is found that ail simplified or stea dy-state methods regularly afford overdimensioned relief cross-sections. As a consequence, unnecessarily large mass flows leave the reactor to enter t he containment system. A balanced design of both plants components is possi ble only with the aid of transient methods. In the case of gas generating r eactions simplified methods also lead to excessively large pressure relief cross-sections. Design with the aid of a transient method for such a reacti on system is rendered difficult by the fact that a conservative submodel ca nnot be used a priori for description of the expansion behaviour. A paramet ric study is then required.