Chiral amplification in columns of self-assembled N,N ',N ''-tris((S)-3,7-dimethyloctyl)benzene-1,3,5-tricarboxamide in dilute solution

Authors
Brunsveld, L Schenning, APHJ Broeren, MAC Janssen, HM Vekemans, JAJM Meijer, EW
Citation
L. Brunsveld et al., Chiral amplification in columns of self-assembled N,N ',N ''-tris((S)-3,7-dimethyloctyl)benzene-1,3,5-tricarboxamide in dilute solution, CHEM LETT, (3), 2000, pp. 292-293
Citations number
10
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
3
Year of publication
2000
Pages
292 - 293
Database
ISI
SICI code
0366-7022(20000305):3<292:CAICOS>2.0.ZU;2-Z
Abstract
Remarkable control of chirality within a long and stable columnar self-asse mbly of N,N',N"-Tris((S)-3,T-dimethyloctyl)benzene-1,3,5-tricarboxamide in dilute solution is achieved by strong, unidirectional hydrogen bonding and cooperative side-chain interactions; IR and CD-spectroscopy have been used to elucidate these features.