A straightforward and novel synthesis of sulfur compounds from aliphatic cyclic ketones and CS2

Authors
Gonzalez-Castro, A Gutierrez-Perez, R Penieres-Carrillo, G Diaz-Torres, E Toscano, RA Moya-Cabrera, M Cabrera-Ortiz, A Alvarez-Toledano, C
Citation
A. Gonzalez-castro et al., A straightforward and novel synthesis of sulfur compounds from aliphatic cyclic ketones and CS2, HETEROAT CH, 11(2), 2000, pp. 120-128
Citations number
22
Categorie Soggetti
Chemistry
Journal title
HETEROATOM CHEMISTRY
ISSN journal
10427163 → ACNP
Volume
11
Issue
2
Year of publication
2000
Pages
120 - 128
Database
ISI
SICI code
1042-7163(2000)11:2<120:ASANSO>2.0.ZU;2-J
Abstract
The reaction of aliphatic cyclic ketones with carbon disulfide under basic conditions, followed by an acidic treatment, unexpectedly afforded-in a mil d, one-pot reaction-sulfur compounds, such as 1,2-dithiole-3-thiones, 1,3-d ithiole-4-thiones, 1,3-dithiin-3-thiones, 1,2,4-trithioles, and dixanthates , instead of the usual conjugated alpha-oxoketene dithiolic acids. (C) 2000 John Wiley & Sons, Inc.