H. Ohji et al., Excess thermodynamic properties of (2-ethoxyethanol+1,4-dioxane or 1,2-dimethoxyethane) at temperatures between (283.15 and 313.15) K, J CHEM THER, 32(3), 2000, pp. 319-328
Measurements of the excess enthalpies H-E at T = 298.15 K and densities at
15 K intervals from T = (283.15 to 313.15) K are reported for (2-ethoxyetha
nol + 1,4-dioxane or 1,2-dimethoxyethane). Excess volumes V-E, excess therm
al expansivities alpha(E), and the pressure derivatives of the excess entha
lpies were estimated from the measured densities. The values of H-E for bot
h systems are positive, However, the values of V-E for the 1,2-dimethoxyeth
ane system are negative, although they are positive for the 1,4-dioxane sys
tem as expected from the sign of H-E. The behaviour of these properties is
discussed in terms of hydrogen bonds and size and shape of the ether molecu
les. (C) 2000 Academic Press.