Addition of HCl to a cluster-bound vinylidene ligand: Preparation and structure of Ru-5(mu(3)-SMe)(mu(3)-CMe)(mu-Cl)(mu-SMe) (mu-PPh2)(2)(CO)(9)center dot PhMe

Authors
Bruce, MI Schulz, M Skelton, BW White, AH
Citation
Mi. Bruce et al., Addition of HCl to a cluster-bound vinylidene ligand: Preparation and structure of Ru-5(mu(3)-SMe)(mu(3)-CMe)(mu-Cl)(mu-SMe) (mu-PPh2)(2)(CO)(9)center dot PhMe, J CLUST SCI, 11(1), 2000, pp. 79-86
Citations number
8
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF CLUSTER SCIENCE
ISSN journal
10407278 → ACNP
Volume
11
Issue
1
Year of publication
2000
Pages
79 - 86
Database
ISI
SICI code
1040-7278(200003)11:1<79:AOHTAC>2.0.ZU;2-M
Abstract
Addition of aqueous HCl to RU5(mu(3)-C = CH2)(mu-SMe)(2)(mu-PPh2)(2)(CO)(10 ) afforded the structurally characterized carbyne complex Ru-5(mu(3)-SMe)(m u(3)-CMe)(mu-Cl)(mu-SME)(mu-PPh2)(2)(CO)(9), formed by addition of H to the vinylidene ligand; a Cl atom bridges an Ru-Ru bond.