Synthesis and crystal structure of the 2-D polymer {Cu(bipy)Pt(CN)(4)}(infinity) and its relationship to the tetranuclear compound [{Cu(bipy)(H2O)Pt(CN)(4)}(2)]center dot 2H(2)O

Authors
Falvello, LR Garde, R Tomas, M
Citation
Lr. Falvello et al., Synthesis and crystal structure of the 2-D polymer {Cu(bipy)Pt(CN)(4)}(infinity) and its relationship to the tetranuclear compound [{Cu(bipy)(H2O)Pt(CN)(4)}(2)]center dot 2H(2)O, J CLUST SCI, 11(1), 2000, pp. 125-133
Citations number
13
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF CLUSTER SCIENCE
ISSN journal
10407278 → ACNP
Volume
11
Issue
1
Year of publication
2000
Pages
125 - 133
Database
ISI
SICI code
1040-7278(200003)11:1<125:SACSOT>2.0.ZU;2-B
Abstract
The reaction of (NBu4)(2)[Pt(CN)(4)] with Cu(NO3)(2). 2.5H(2)O and bipy in stoichiometric ratio in methanol solution yields the 2-D polymer {Cu(bipp)P t(CN)(4)}(infinity). The influence of water molecules and hydrogen bonding on the formation of a 2-D polymeric structure versus a tetranuclear cluster from "Cu(bipy)Pt(CN)(4)" units is discussed.