A water soluble methanofullerene derivative: synthesis, micellar aggregation in aqueous solutions, and incorporation in sol-gel glasses for optical limiting applications
D. Felder et al., A water soluble methanofullerene derivative: synthesis, micellar aggregation in aqueous solutions, and incorporation in sol-gel glasses for optical limiting applications, J MAT CHEM, 10(4), 2000, pp. 887-892
Amphiphilic methanofullerene derivative 1 is water soluble and micellar agg
regation has been evidenced by small-angle X-ray scattering measurements an
d UV/Vis spectroscopy. Thanks to the high solubility of 1 in polar solvents
widely used in sol-gel processing, successful inclusion of 1 in the sol-ge
l could be easily achieved. The optical limiting properties of the doped so
l-gel samples have been evaluated and a fast S-1-S-0 relaxation has been ob
served for these samples. This observation appears to be consistent with th
e presence of micellar aggregates of 1 in the sol-gel. Indeed, the interact
ions between the fullerene spheres of neighbouring molecules in the cluster
s may be at the origin of this fast S-1-S-0 relaxation as already shown in
solid C-60-films.