Transition state for beta-elimination of hydrogen from alkoxy groups on metal surfaces

Citation
Aj. Gellman et al., Transition state for beta-elimination of hydrogen from alkoxy groups on metal surfaces, J PHYS CH A, 104(11), 2000, pp. 2476-2485
Citations number
27
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF PHYSICAL CHEMISTRY A
ISSN journal
10895639 → ACNP
Volume
104
Issue
11
Year of publication
2000
Pages
2476 - 2485
Database
ISI
SICI code
1089-5639(20000323)104:11<2476:TSFBOH>2.0.ZU;2-9
Abstract
Experimental investigations of beta-hydrogen elimination from alkoxy and al kyl groups bound to a Cu(111) surface have been coupled with computational studies of gas-phase analogues to provide insight into the transition state for catalytic hydrogenation and dehydrogenation on metal surfaces. Previou s studies have shown that fluorination increases the activation barrier (De lta E-act) to beta-hydrogen elimination in ethoxy groups (RCH2O(ad) --> RCH =O-(ad) + H-(ad), where R = CH3, CFH2, CHF2, CF3) and propyl groups (RCH2CH 2,(ad) --> RCH=CH2,(ad) + H-(ad), where R = CH3, CF3) on the Cu(111) surfac e. The increase in barrier height with increasing fluorination was attribut ed to the inductive influence of fluorine, which energetically destabilizes a hydride-like transition state of the form [RCdelta+...Hdelta-](not equal ). In this paper, deuterium kinetic isotope effects (DKIE) show that fluori nation does not alter the mechanism for beta-hydrogen elimination from etho xy groups. Furthermore, the DKIE measurements confirm that the effects of f luorine on the kinetics of beta-hydrogen elimination do not result from the change in mass when hydrogen is substituted by fluorine. A systematic stud y of fluorine substitution of surface-bound isopropoxy groups reveals combi ned steric and electronic effects. An excellent correlation is found betwee n the Delta E-act for beta-hydrogen elimination in adsorbed alkoxy groups a nd the calculated reaction energetics (Delta H-rxn) for gas-phase dehydroge nation of fluorinated alcohols in trans antiperiplanar conformations (e.g., RCH2OH(g) --> RCH=O-(g) + H-2,H-(g),H- where the hydroxyl hydrogen is anti periplanar to a carbon and the oxygen is antiperiplanar to a fluorine). Ham mett plots for P-hydrogen elimination give a reaction parameter of rho = -2 6. These correlations both suggest that the transition state for beta-hydro gen elimination develops a greater partial positive charge on the carbinol carbon than is found in the adsorbed reactant. Furthermore, the transition state is energetically late in the reaction coordinate for beta-hydrogen el imination.