The intercalation reaction of 1,10-phenanthroline with FePS3 in ethanol and
in the presence of anilinium chloride has been monitored in detail with th
e X-ray powder diffraction (XRD) method to study the reaction mechanism. It
is revealed that during the intercalation period there are three phases: t
he 001 phase (corresponding to the perpendicular orientation of the 1,10-ph
enanthroline ring with the layer of the host FePS3), the 001' phase (standi
ng for the parallel orientation of the 1,10-phenanthroline ring with the la
yer), and the 001" phase (pristine FePS3), but as the period of the reactio
n is prolonged, the 001' and 001" phases diminish gradually and finally dis
appear, and the 001 phase is intensified and a complete intercalate is obta
ined for Series A, in which excess 1,10-phenanthroline is used. However, fo
r Series B in which the optimum amount of 1,10-phenanthroline is used, the
001 and 001" phases diminish gradually, and another intercalate is obtained
that exhibits the 001' phase. Moreover, if the amount of phenanthroline us
ed in the reaction is more than that in Series B but not in excess, another
intercalate containing 001 and 001' phases is obtained. In these intercala
tion reactions, the results of IR spectroscopy indicate that anilinium chlo
ride serves only as the source of protons for 1,10-phenanthroline, but 1,10
-phenanthroline acts as both the complexing agent of Fe2+ ions removed from
FePS3, confirmed by UV spectra of the filtrates, and the inserted guest, s
ome of which exists in the form of protonated cation to maintain the charge
balance of the intercalates. From the experimental evidence we find that t
he arranged orientation of 1,10-phenanthroline between the layers is contro
lled by the amount of guest used in the reaction, and a possible intercalat
ion mechanism is proposed for the reaction. (C) 2000 Academic Press.