Oe. Sherif et al., Thermodynamic parameters of some Schiff bases derived from 5,7-dihydroxy-6-formyl-2-methylbenzopyran-4-one, J THERM ANA, 59(3), 2000, pp. 913-926
Potentiometric studies on Schiff bases derived from 5,7-dihydroxy-6-formyl-
2-methylbenzopyran- 4-one were carried out at different ionic strengths (0.
02, 0.04, 0.06, 0.10 and 0.14 M NaCl), at different temperatures (25, 35, 4
5 and 55 degrees C) and in ethanol-water media of varying compositions (60,
70, 80 and 90% v/v). The ionization constants of the Schiff bases were inv
estigated in the presence of different organic solvents (70% v/v), e.g. met
hanol, ethanol, n-propanol, isopropanol, acetone, DMSO and DMF-water media.
The thermodynamic parameters (Delta G, Delta H and Delta S) were also calc
ulated.