SYNTHESIS AND CHARACTERIZATION OF OPTICALLY-ACTIVE CYCLIC 6,6'-DINITRO-1,1'-BINAPHTHYL-2,2'-DIETHERS

Authors
VANES JJGS BIEMANS HAM MEIJER EW
Citation
Jjgs. Vanes et al., SYNTHESIS AND CHARACTERIZATION OF OPTICALLY-ACTIVE CYCLIC 6,6'-DINITRO-1,1'-BINAPHTHYL-2,2'-DIETHERS, Tetrahedron : asymmetry, 8(11), 1997, pp. 1825-1831
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
8
Issue
11
Year of publication
1997
Pages
1825 - 1831
Database
ISI
SICI code
0957-4166(1997)8:11<1825:SACOOC>2.0.ZU;2-H
Abstract
A series of racemic and enantiomerically pure 6,6'-dinitro-1,1'-binaph thyl-2,2'-diethers 1 have been synthesized by the nitration of the cor responding cyclic ethers and both the reactivity of nitration and the (chir)optical properties proved to be very sensitive for the chain len gth of the ether bridge. (C) 1997 Elsevier Science Ltd.