Structure of products of H-H and C-H bond activation by Ni atom, Ni-2 cluster, and Ni-porphyrin complex of Ni-2 cluster

Authors
Mamaev, VM Gloriozov, IP Lemenovskii, DA Zernova, EV
Citation
Vm. Mamaev et al., Structure of products of H-H and C-H bond activation by Ni atom, Ni-2 cluster, and Ni-porphyrin complex of Ni-2 cluster, KINET CATAL, 41(1), 2000, pp. 33-37
Citations number
35
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
KINETICS AND CATALYSIS
ISSN journal
00231584 → ACNP
Volume
41
Issue
1
Year of publication
2000
Pages
33 - 37
Database
ISI
SICI code
0023-1584(200001/02)41:1<33:SOPOHA>2.0.ZU;2-3
Abstract
New catalytic systems based on porphyrin complexes of Ni-2 cluster and capa ble of activating C-H and H-H bonds are proposed. DFT calculations showed t hat a Ni-2 cluster can coordinate Ni-porphyrin with a considerable gain in energy. The structures of the products of methane and hydrogen activation w ere discussed.