E. Hattemer et al., Synthesis and characterization of novel multifunctional high-T-g photorefractive materials obtained via reactive precursor polymers, MACROMOLEC, 33(6), 2000, pp. 1972-1977
We describe the synthesis of a new class of high-T-g multifunctional photor
efractive polymers. They were obtained by radical copolymerization of methy
l vinyl isocyanate and various N-substituted maleimides. Hole transporting
carbazole moieties were attached though a variety of alkyl and phenyl space
rs to the imide positions of the maleimides. In a polymer analogous reactio
n the reactive isocyanate groups of the precursor polymers were reacted wit
h different; hydroxyalkyl-terminated nonlinear optical chromophores. Two az
o chromophores including dispersed red-1 and one pyrazolone dye were used.
The resulting materials have been characterized by means of GPC. DSC, and U
V/vis spectroscopy. All materials are amorphous and possess excellent solub
ility in common solvents such as chloroform and THF. Molecular weights rang
e between 20 and 272 kg/mol. The glass-transition temperatures vary between
60 and 194 degrees C, depending on the length and the nature of the spacer
groups between the maleimide rings and the carbazole moieties. Chromophore
contents up to 44 mol % have been realized. Holographic experiments were p
erformed on a device made from a multifunctionalized PR polymer plasticized
such that the glass-transition temperature was T-g = 80 degrees C. The mat
erial was prepoled Co break inversion symmetry and to induce macroscopic el
ectrooptical properties. The steady-state gain coefficient (approximate to
7 cm(-1)) and diffraction efficiency of this device (approximate to 1%) wer
e reduced compared with that of low-T-g materials. This is because orientat
ional enhancement effects observed in low-T-g materials are excluded in tal
e high-T-g regime. For the grating formation a dominant response time tau(1
) = 100 ms was found.