ETA(3)-ETA(5) INTERCONVERSION VS WEAK BONDING INTERACTIONS IN NEUTRALMOLYBDENUM(II) COMPLEXES

Authors
CHOWDHURY SK SAMANTA U PURANIK VG SARKAR A
Citation
Sk. Chowdhury et al., ETA(3)-ETA(5) INTERCONVERSION VS WEAK BONDING INTERACTIONS IN NEUTRALMOLYBDENUM(II) COMPLEXES, Organometallics, 16(12), 1997, pp. 2618-2622
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
12
Year of publication
1997
Pages
2618 - 2622
Database
ISI
SICI code
0276-7333(1997)16:12<2618:EIVWBI>2.0.ZU;2-9
Abstract
In a set of structurally related Mo(II) ct-allyl complexes with a conj ugated double bond appended to the allyl group, a weak bonding interac tion such as B-H-Mo or C-H-Mo appears to prevent eta(3) to eta(5) inte rconversion. Structural assignments are made on the basis of NMR data, and crystal structure solutions are carried out for two of the comple xes.