SYNTHESIS AND CHARACTERIZATION OF A NOVEL DIARYLGERMYLENE CONTAINING ELECTRON-WITHDRAWING GROUPS

Authors
BENDER JE HOLL MMB KAMPF JW
Citation
Je. Bender et al., SYNTHESIS AND CHARACTERIZATION OF A NOVEL DIARYLGERMYLENE CONTAINING ELECTRON-WITHDRAWING GROUPS, Organometallics, 16(12), 1997, pp. 2743-2745
Citations number
42
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
12
Year of publication
1997
Pages
2743 - 2745
Database
ISI
SICI code
0276-7333(1997)16:12<2743:SACOAN>2.0.ZU;2-6
Abstract
The fluoroarylgermylene is[2,4,6-tris(trifluoromethyl)phenyl]germanium (II) was synthesized by the reaction of 2 equiv of [2,4,6-tris(trifluo romethyl)phenyl]lithium with GeCl2 . dioxane. This monomeric germylene has good thermal stability, despite having the least sterically encum bering set of stabilizing ligands of any alkyl germylene isolated to d ate.