SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF S[BIS(TRIMETHYLSILYL)METHYL]PHENYL)DIBROMOPLUMBANE - THE FIRST MONOMERIC DIORGANODIHALOPLUMBANE INTHE CRYSTALLINE STATE

Authors
KANO N TOKITOH N OKAZAKI R
Citation
N. Kano et al., SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF S[BIS(TRIMETHYLSILYL)METHYL]PHENYL)DIBROMOPLUMBANE - THE FIRST MONOMERIC DIORGANODIHALOPLUMBANE INTHE CRYSTALLINE STATE, Organometallics, 16(12), 1997, pp. 2748-2750
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
12
Year of publication
1997
Pages
2748 - 2750
Database
ISI
SICI code
0276-7333(1997)16:12<2748:SAXCOS>2.0.ZU;2-O
Abstract
Reaction of a plumbylene Tbt(2)Pb: (1) with carbon tetrabromide in THF gave the first crystallographically characterized dibromoplumbane Tbt (2)PbBr(2) (2) bearing two 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt) groups. The X-ray crystallographic analysis revealed that 2 has a monomeric structure with a distorted tetrahedral lead center.