CARBON-SELENIUM BOND-CLEAVAGE BY A RHODIUM COMPLEX

Authors
VICIC DA MYERS AW JONES WD
Citation
Da. Vicic et al., CARBON-SELENIUM BOND-CLEAVAGE BY A RHODIUM COMPLEX, Organometallics, 16(12), 1997, pp. 2751-2753
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
12
Year of publication
1997
Pages
2751 - 2753
Database
ISI
SICI code
0276-7333(1997)16:12<2751:CBBARC>2.0.ZU;2-3
Abstract
The complex CpRh(PMe3)PhH (Cp* = C5Me5) reacts thermally with selenop hene to give a C-Se insertion product. X-ray structural characterizati on shows a planar 6-membered ring containing a localized butadiene str ucture. Se-77 NMR studies display an. upfield resonance consistent wit h a non-aromatic metallaselenabenzene ring.