A new preparative method for allylic indium(III) reagents by reductive transmetalation of pi-allylpalladium(II) with indium(I) salts
Citation
S. Araki et al., A new preparative method for allylic indium(III) reagents by reductive transmetalation of pi-allylpalladium(II) with indium(I) salts, ORG LETT, 2(6), 2000, pp. 847-849
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
SICI code
1523-7060(20000323)2:6<847:ANPMFA>2.0.ZU;2-S
Abstract
A reductive transmetalation of the pi-allylpalladium(II) complexes, generat
ed in situ from a catalytic amount of a palladium(0) complex and a variety
of allylic substrates, with indium(I) salts proceeded smoothly in various s
olvents, providing a new route for allylindium(III) reagents.