Heavy ion induced inner shell ionization produces multiple vacancies in the
outer shells (M, N etc.) simultaneous to vacancies in the inner-shells (vi
z. L-shell), which in turn create a very complicated electronic configurati
on. Three projectiles N-(2+,3+), Si-(7+,8+) and Ti-(10+,11+) ion beams havi
ng a range of 0.3 to 3.5 MeV/u were bombarded on a thin rare earth target o
f Yb. The recorded L X-ray spectra of Yb have been analyzed in the light of
multiple ionization produced due to the heavy ion impact. The outer-shell
vacancies acting as spectator vacancies cause a shift in the energy of the
various emitted L X-ray diagram lines. A comparison of the shifts in the en
ergies of the various L X-ray transitions of Yb due to the impact of these
projectiles, from standard values and that due to proton impact along with
the deviation of the intensity ratios from single hole branching ratios, re
veal a dependence of multiple ionization on the projectile atomic number (Z
) and energy. A further comparison of the degree of multiple ionization pro
duced in Yb, evident by the number of spectator vacancies produced due to t
he impact of projectiles with 7 less than or equal to Z less than or equal
to 22 and overlapping MeV/u range lead to explicit conclusions regarding th
e probability of multiple vacancy production in outer shells simultaneous t
o a single L-shell vacancy for such projectile target combinations.