We observe in GaN/AlxGa1-xN quantum wells with varying aluminum concentrati
on strong electric fields whose amplitudes are significantly larger than th
ose observed before in comparable structures fabricated at higher growth te
mperatures. We show that the measured fields are clearly stronger than what
is expected based on piezoelectric effects alone, which constitutes a dire
ct experimental proof of the existence of important spontaneous polarizatio
n effects in the GaN/AlxGa1-xN heterostructure system.