Quantum confinement in GaAs1-xNx/GaAs quantum wells (0.009<x<0.045) is stud
ied using electroreflectance measurements. Formation of an impurity band du
e to heavy nitrogen doping and the quantum confinement of an electron belon
ging to such an impurity band have been demonstrated. The formation of an i
mpurity band results in an unusual variation in the electron effective mass
with nitrogen doping.