Influence of fluctuations on the phase diagram of chiral nematic liquid crystals

Citation
J. Englert et al., Influence of fluctuations on the phase diagram of chiral nematic liquid crystals, PHYS REV E, 61(3), 2000, pp. 2759-2768
Citations number
34
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW E
ISSN journal
1063651X → ACNP
Volume
61
Issue
3
Year of publication
2000
Pages
2759 - 2768
Database
ISI
SICI code
1063-651X(200003)61:3<2759:IOFOTP>2.0.ZU;2-H
Abstract
In a recent paper [Phys. Rev. Lett. 81, 1457 (1998)], we demonstrated that the phase diagram of the liquid crystalline blue phases, as calculated by m eans of Landau-de Gennes theory, displays serious deficiencies, which can o nly be removed if fluctuations are taken into account within statistical fi eld theory. Here we present details of the calculations. The influence of f luctuations is treated self-consistently within a first order cumulant expa nsion. The square Delta of the inverse correlation length of the alignment tensor field is introduced as an order parameter. In a simplified model two phases of differing Delta. appear at high chiralities, which are identifie d as the isotropic phase and the isostructural blue fog. The relationship b etween the cumulant expansion and the Brazovskii method is illuminated.