We present a theoretical and experimental study of the production of very h
igh order photoelectrons from alkali metal atoms interacting with intense,
midinfrared radiation. The strength of this process shows an unexpectedly s
trong species dependence. We find that this dependence can be explained via
the difference in the cross section for electron-ion scattering from the d
ifferent atoms. This allows us to directly relate the high energy portion o
f the photoelectron spectrum to specific features of the electron-ion poten
tial.