Doppler splitting of in-flight anger decay of dissociating oxygen molecules: The localization of delocalized core holes

Authors
Bjorneholm, O Bassler, M Ausmees, A Hjelte, I Feifel, R Wang, H Miron, C Piancastelli, MN Svensson, S Sorensen, SL Gel'mukhanov, F Agren, H
Citation
O. Bjorneholm et al., Doppler splitting of in-flight anger decay of dissociating oxygen molecules: The localization of delocalized core holes, PHYS REV L, 84(13), 2000, pp. 2826-2829
Citations number
29
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
84
Issue
13
Year of publication
2000
Pages
2826 - 2829
Database
ISI
SICI code
0031-9007(20000327)84:13<2826:DSOIAD>2.0.ZU;2-Y
Abstract
By exploiting the core-excitation-induced dissociation of O-2, we find that the Auger emission exhibits a Doppler-like energy shift. We show this to b e a manifestation of localization of the core hole and propose that the pro blem of core-hole localization versus delocalization in core-hole spectrosc opies may be resolved by considering the nature of the measurement.