Thomson scattering measurements are presented which demonstrate conclusivel
y the occurrence of the Langmuir decay instability (LDI) in a laser-produce
d plasma experiment. Both products of the instability, the ion acoustic wav
e and the electron plasma wave, were simultaneously observed and identified
with their spectral characteristics. The secondary decay of the LDI-genera
ted electron plasma wave, into another Langmuir wave and an ion acoustic wa
ve, has been observed for the first time. The connection with growth and sa
turation of the stimulated Raman instability is discussed.