Quantitative aspects of the effects of halide and azide ions on the acid-catalyzed hydrolysis of (+/-)-7 beta-8 alpha-dihydroxy-9 alpha,10 alpha-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene

Authors
Lin, B Doan, L Yagi, H Jerina, DM Whalen, D
Citation
B. Lin et al., Quantitative aspects of the effects of halide and azide ions on the acid-catalyzed hydrolysis of (+/-)-7 beta-8 alpha-dihydroxy-9 alpha,10 alpha-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene, POLYCYCL AR, 16(1-4), 1999, pp. 79-88
Citations number
15
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYCYCLIC AROMATIC COMPOUNDS
ISSN journal
10406638 → ACNP
Volume
16
Issue
1-4
Year of publication
1999
Pages
79 - 88
Database
ISI
SICI code
1040-6638(1999)16:1-4<79:QAOTEO>2.0.ZU;2-3
Abstract
Mechanisms of the acid-catalyzed reactions of (+/-)-7 beta, 8 alpha-dihydro xy-9 alpha, 10 alpha-epoxy-7, 8, 9, 10-tetrahydrobenzo[a]pyrene (1) in 1:9 dioxane-water solutions containing varying concentrations of KCl, KBr, NaI, NaN3 and NaClO4 are discussed.