Salt-like complex compounds {Mo3S7[(C2H5)(2)NCS2](3)}(+)[M(1,2-C2B9H11)(2)](-) [M = Fe(III), Co(III), or Ni(III)]: IR, Raman, B-11 NMR, UV, and X-rayphotoelectron studies

Authors
Il'inchik, EA Volkov, VV Volkov, OV Asanov, IP Kolesov, BA
Citation
Ea. Il'Inchik et al., Salt-like complex compounds {Mo3S7[(C2H5)(2)NCS2](3)}(+)[M(1,2-C2B9H11)(2)](-) [M = Fe(III), Co(III), or Ni(III)]: IR, Raman, B-11 NMR, UV, and X-rayphotoelectron studies, RUSS J C CH, 26(3), 2000, pp. 185-194
Citations number
33
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
26
Issue
3
Year of publication
2000
Pages
185 - 194
Database
ISI
SICI code
1070-3284(200003)26:3<185:SCC{>2.0.ZU;2-Y
Abstract
The {Mo-3(mu(3)-S)(mu(2)-S-2)(3)[(C2H5)(2)NCS2](3)}(+){M[eta(5)-(3)-1,2-C2B 9H11](2)}(-) [M = Fe(III), Co(III), or Ni(III)] compounds were synthesized. A comparative study of the compounds was performed by IR, Raman, B-11 NMR, UV, and X-ray photoelectron spectroscopies. In the crystal state, the anio n and cation are linked by the hydrogen bond S-H-B, whose strength increase s in the order [Ni(C2B9H11)(2)](-)(d(7)) < [Co(C2B9H11)(2)](-)(d(6)) < [Fe( C2B9H11)(2)](-)(d(5)).