Complexation of Pd(II) and Pt(II) with silica-supported thiosemicarbazide

Authors
Kravchenko, OV Yatsimirskii, KB Talanova, GG Belyakova, LA Kozachkova, AN
Citation
Ov. Kravchenko et al., Complexation of Pd(II) and Pt(II) with silica-supported thiosemicarbazide, RUSS J C CH, 26(3), 2000, pp. 199-204
Citations number
10
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
26
Issue
3
Year of publication
2000
Pages
199 - 204
Database
ISI
SICI code
1070-3284(200003)26:3<199:COPAPW>2.0.ZU;2-S
Abstract
It is shown that the binding of Pd(II) and Pt(II) from aqueous solutions of their salts by thiosemicarbazide immobilized on a Silochrom surface gives rise to the complexes whose composition substantially differs from the comp osition of their analogues in solutions. The binding of Pd(II) from chlorid e solutions results in the polynuclear complexes containing bridging chlori ne atoms.