(Acac)Pd(C-3-Acac)center dot PR3+BF3OEt2 system in the presence of hexene-1: Reaction mechanism

Authors
Tkach, VS Ratovskii, GV Gomboogiin, M Mes'ef, M Tyukalova, OV Zelinskii, SN Shmidt, FK
Citation
Vs. Tkach et al., (Acac)Pd(C-3-Acac)center dot PR3+BF3OEt2 system in the presence of hexene-1: Reaction mechanism, RUSS J C CH, 26(3), 2000, pp. 211-219
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
26
Issue
3
Year of publication
2000
Pages
211 - 219
Database
ISI
SICI code
1070-3284(200003)26:3<211:(DPSIT>2.0.ZU;2-U
Abstract
The interactions between the components of the catalytic (Acac)Pd(C-3-Acac) PR3 + BF3OEt2 (Acac = acetylacetonate) systems, including the reactions in the presence of hexene-l, were studied by the IR and UV spectroscopic metho ds. The consecutive steps of formation of the active H(L)Pd(P)F . BF2X (P = PR3; X = OH, F; and L = hexene-1) complexes were determined.