Vs. Tkach et al., (Acac)Pd(C-3-Acac)center dot PR3+BF3OEt2 system in the presence of hexene-1: Reaction mechanism, RUSS J C CH, 26(3), 2000, pp. 211-219
The interactions between the components of the catalytic (Acac)Pd(C-3-Acac)
PR3 + BF3OEt2 (Acac = acetylacetonate) systems, including the reactions in
the presence of hexene-l, were studied by the IR and UV spectroscopic metho
ds. The consecutive steps of formation of the active H(L)Pd(P)F . BF2X (P =
PR3; X = OH, F; and L = hexene-1) complexes were determined.